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411 REFERENCE · Wikibooks

Physical Chemistry/State Functions

Reference material by Wikibooks contributors. This retains its source identity and is not 411 news reporting.

The following demonstrates what's a state function and what's not a state function. is not exact differential for a gas obeying van der Waals' equation, but is as demonstrated below: We assume quasistatic situation, so . Now, you take the cross partial derivatives. They are not equal; hence, is not exact differential (not a state function). However, if we take it will be exact differential (a state function). Take the cross partial derivatives. Both are equal making exact differential (a state function). fr:Chimie physique/Fonction d'état