Chemical Sciences: A Manual for CSIR-UGC National Eligibility Test for Lectureship and JRF/Mass-analyzed ion kinetic energy spectrometry

Mass-analyzed ion kinetic energy spectrometry (MIKES) is a mass spectrometry technique by which mass spectra are obtained from a sector instrument that incorporates at least one magnetic sector plus one electric sector in reverse geometry (the beam first enters the magnetic sector).Soltero-Rigau E, Kruger TL, Cooks RG Identification of barbiturates by chemical ionization and mass-analyzed ion kinetic energy spectrometry Anal. Chem. 49 3 435–42 1977 842853 10.1021/ac50011a027Easton C, Johnson DW, Poulos A Determination of phospholipid base structure by CA MIKES mass spectrometry J. Lipid Res. 29 1 109–12 1988 3356947 Cooks RG, Kondrat RW, Youssefi M, McLaughlin JL Mass-analyzed ion kinetic energy (MIKE) spectrometry and the direct analysis of coca J Ethnopharmacol 3 2-3 299–312 1981 7242113 10.1016/0378-8741(81)90060-X The accelerating voltage V, and the magnetic field B, are set to select the precursor ions of a particular m/z. The precursor ions then to dissociate or react in an electric field-free region between the two sectors. The ratio of the kinetic energy to charge of the product ions are analyzed by scanning the electric sector field E. The width of the product ion spectrum peaks is related to the kinetic energy release distribution for the dissociation process. Analysis of a mass-analyzed ion kinetic energy profile. II. Systematic determination of the kinetic energy release distribution Rapid Communications in Mass Spectrometry 1992 Chul Yeh Myung Soo Kim 6 4 293–297 10.1002/rcm.1290060414 http://www3.interscience.wiley.com/cgi-bin/fulltext/110446642/PDFSTART PDF 2008-03-30 References Bibliography Jacques Momigny; Eugen Illenberger Gaseous Molecular Ions: An Introduction To Elementary Processes Induced By Ionization (Topics in Physical Chemistry) Steinkopff Darmstadt 1999 3-7985-0870-4