411 REFERENCE · Wikibooks
General Chemistry/Properties of elements are periodic
Reference material by Wikibooks contributors. This retains its source identity and is not 411 news reporting.
The periodic table of the chemical elements is a display of known chemical elements, arranged by electron structure so that many chemical property|chemical properties vary regularly across the table.
The original table was created without a knowledge of the inner structure of atom|atoms: if one orders the elements by atomic mass, and then plots certain other properties against atomic mass, one sees an undulation or periodicity to these properties as a function of atomic mass.
The first to recognize these regularities was the German chemist Johann Wolfgang Döbereiner who, in 1829, noticed a number of triads of similar elements:
Some triads Element Atomic mass Density chlorine 35.5 0.00156 g/cm3 bromine 79.9 0.00312 g/cm3 iodine 126.9 0.00495 g/cm3 calcium 40.1 1.55 g/cm3 strontium 87.6 2.6 g/cm3 barium 137 3.5 g/cm3
This was followed by the English chemist John Alexander Reina Newlands, who in 1865 noticed that the elements of similar type recurred at intervals of eight, which he likened to the octave|octaves of music, though his law of octaves was ridiculed by his contemporaries. Finally, in 1869, the German Lothar Meyer and the Russian chemist Dmitry Ivanovich Mendeleev almost simultaneously developed the first periodic table, arranging the elements by mass. However, Mendeleev plotted a few elements out of strict mass sequence in order to make a better match to the properties of their neighbours in the table, corrected mistakes in the values of several atomic masses, and predicted the existence and properties of a few new elements in the empty cells of his table. Mendeleev was later vindicated by the discovery of the electronic structure of the elements in the late 19th century|19th and early 20th century.
Lists of the elements List of elements by name|by name, List of elements by symbol|by symbol, and List of elements by number|by atomic number are available.
The following figure shows the currently known periodic table of the elements.
Each element is listed by its atomic number and chemical symbol.
Elements in the same column ("periodic table group|group") are chemically similar.
Group 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 Period 1 1H 2He 2 3Li 4Be 5B 6C 7N 8O 9F 10Ne 3 11Na 12Mg 13Al 14Si 15P 16S 17Cl 18Ar 4 19K 20Ca 21Sc 22Ti 23V 24Cr 25Mn 26Fe 27Co 28Ni 29Cu 30Zn 31Ga 32Ge 33As 34Se 35Br 36Kr 5 37Rb 38Sr 39Y 40Zr 41Nb 42Mo 43Tc 44Ru 45Rh 46Pd 47Ag 48Cd 49In 50Sn 51Sb 52Te 53I 54Xe 6 55Cs 56Ba * 71Lu 72Hf 73Ta 74W 75Re 76Os 77Ir 78Pt 79Au 80Hg 81Tl 82Pb 83Bi 84Po 85At 86Rn 7 87 Fr 88Ra ** 103Lr 104Rf 105Db 106Sg 107Bh 108Hs 109Mt 110Ds 111Uuu 112Uub 113Uut 114Uuq 115Uup 116Uuh 117Uus 118Uuo * Lanthanides 57La 58Ce 59Pr 60Nd 61Pm 62Sm 63Eu 64Gd 65Tb 66Dy 67Ho 68Er 69Tm 70Yb ** Actinides 89Ac 90Th 91Pa 92U 93Np 94Pu 95Am 96Cm 97Bk 98Cf 99Es 100Fm 101Md 102No
+ Chemical Series of the Periodic Table Alkali metals Alkaline earths Lanthanide Actinidea Transition metals Poor metals Metalloids Nonmetals Halogens Noble gases
Colour coding for atomic numbers:
Elements numbered in blue are liquids at room temperature;
those in green are gases at room temperature;
those in black are solid at room temperature;
those in red are synthetic and do not occur naturally (all are solid at room temperature).
those in gray have not yet been discovered (they also have muted fill colors indicating the likely chemical series they would fall under).
The number of electron shell|electron shells an atom has determines what period it belongs to. Each shell is divided into different subshells,
which as atomic number increases are filled in roughly this order:
1s
2s 2p
3s 3p
4s 3d 4p
5s 4d 5p
6s 4f 5d 6p
7s 5f 6d 7p
8s 5g 6f 7d 8p
...
Hence the structure of the table. Since the outermost electrons determine chemical properties, those tend to be similar within groups. Elements adjacent to one another within a group have similar physical properties, despite their significant differences in mass. Elements adjacent to one another within a period have similar mass but different properties.
For example, very near to nitrogen (N) in the second period of the chart are carbon (C) and oxygen (O).
Despite their similarities in mass (they differ by only a few atomic mass units), they have extremely different properties, as can be seen by looking at their allotrope|allotropes: diatomic oxygen is a gas that supports burning, diatomic nitrogen is a gas that does not support burning, and carbon is a solid which can be burnt (yes, diamond|diamonds can be burnt!).
In contrast, very near to chlorine (Cl) in the next-to-last group in the chart (the halogen|halogens) are fluorine (F) and bromine (Br).
Despite their dramatic differences in mass within the group, their allotropes have very similar properties:
They are all highly corrosion|corrosive (meaning they combine readily with metal|metals to form metal halide salt|salts); chlorine and fluorine are gases, while bromine is a very low-boiling liquid; chlorine and bromine at least are highly colored.