1,6-Hexanediol diglycidyl ether

Glycidyl ether 1,6-Hexanediol diglycidyl ether.png 2,2′-[Hexane-1,6-diylbis(oxymethylene)]bis(oxirane) 1,6-Hexanediol diglycidyl ether 1,6-Bis(2,3-epoxypropoxy)hexane; 16096-31-4 77541 240-260-4 85960 1S/C12H22O4/c1(3-5-13-7-11-9-15-11)2-4-6-14-8-12-10-16-12/h11-12H,1-10H2 WTYYGFLRBWMFRY-UHFFFAOYSA-N C1C(O1)COCCCCCCOCC2CO2 12 22 4 1,6-Hexanediol diglycidyl ether https://pubchem.ncbi.nlm.nih.gov/compound/85960#section=Safety-and-Hazards pubchem.ncbi.nlm.nih.gov 9 April 2022 en 07 Warning 315 317 319 412 261 264 264+265 272 273 280 302+352 305+351+338 321 332+317 333+313 337+317 362+364 501 1,6-Hexanediol diglycidyl ether is an organic chemical in the glycidyl ether family. It is an aliphatic compound that is a colorless liquid. It has two epoxide (oxirane) groups per molecule. Its main use is in modifying epoxy resins especially viscosity reduction whilst flexibilizing.Jagtap Ameya Rajendra More Aarti 2022-08-01 Developments in reactive diluents: a review https://doi.org/10.1007/s00289-021-03808-5 Polymer Bulletin en 79 8 5667–5708 10.1007/s00289-021-03808-5 235678040 1436-2449 subscription It is REACH registered.Substance Information - ECHA https://echa.europa.eu/substance-information/-/substanceinfo/100.036.585 2022-04-09 echa.europa.eu en-GB Manufacture 1,6-Hexanediol and epichlorohydrin are reacted in the presence of a Lewis acid as catalyst to form a halohydrin: each hydroxyl group of the diol reacts with an epoxide on epichlorohydrin. This process is followed by washing with sodium hydroxide to re-form the epoxide rings in a dehydrochlorination reaction.Yi Wen-Jing Feng Zhi-Hua Zhang Qin-Fang Zhang Ji Li Ling-Dong Zhu Wen Yu Xiao-Qi 2011-03-16 Diol glycidyl ether-bridged cyclens: preparation and their applications in gene delivery Organic & Biomolecular Chemistry en 9 7 2413–2421 10.1039/C0OB00879F 21340090 1477-0539Crivello James V. 2006 Design and synthesis of multifunctional glycidyl ethers that undergo frontal polymerization Journal of Polymer Science Part A: Polymer Chemistry 44 21 6435–6448 10.1002/pola.21761 2006JPoSA..44.6435C 0887-624X One of the quality control tests would involve measuring the Epoxy value by determination of the epoxy equivalent weight. Uses Its main use is for reduction of viscosity in epoxy resin systems - it is thus an epoxy reactive diluent. The chain length helps give some degree of flexibility as an epoxy resin has rigid aromatic rings which are planar.Monte Salvatore J. Plastics Additives Diluents and viscosity modifiers for epoxy resins Polymer Science and Technology Series 1998 1 211–216 Pritchard Geoffrey Dordrecht Springer Netherlands en 10.1007/978-94-011-5862-6_24 978-94-011-5862-6 These systems may then be formulated into CASE applications: Coatings,Howarth G.A "Synthesis of a legislation compliant corrosion protection coating system based on urethane, oxazolidine and waterborne epoxy technology" page 23 Master of Science Thesis April 1997 Imperial College London Adhesives, Sealants, Elastomers, and composite materials. The use of the diluent does effect mechanical properties and microstructure of epoxy resins.Khalina Morteza Beheshty Mohammad Hosain Salimi Ali 2019-08-01 The effect of reactive diluent on mechanical properties and microstructure of epoxy resins https://doi.org/10.1007/s00289-018-2577-6 Polymer Bulletin en 76 8 3905–3927 10.1007/s00289-018-2577-6 105389177 1436-2449 subscription Pastarnokienė Liepa Jonikaitė-Švėgždienė Jūratė Lapinskaitė Neringa Kulbokaitė Rūta Bočkuvienė Alma Kochanė Tatjana Makuška Ričardas 2023-07-01 The effect of reactive diluents on curing of epoxy resins and properties of the cured epoxy coatings https://doi.org/10.1007/s11998-022-00737-4 Journal of Coatings Technology and Research en 20 4 1207–1221 10.1007/s11998-022-00737-4 256749849 1935-3804 subscription Toxicity The toxicity is fairly well understood.Berdasco Nancy Anne M. Epoxy Compounds: Aromatic Diglycidyl Ethers, Polyglycidyl Ethers, Glycidyl Esters, and Miscellaneous Epoxy Compounds 2012-08-17 https://onlinelibrary.wiley.com/doi/10.1002/0471435139.tox083.pub2 Patty's Toxicology 491–528 Bingham Eula Hoboken, NJ, USA John Wiley & Sons, Inc. en 10.1002/0471435139.tox083.pub2 978-0-471-12547-1 2022-07-28 Waechter John M. Cohrssen Barbara Powell Charles H. subscription It is classed as a skin irritant, skin sensitizer, allergen and has caused contact dermatitis.Angelini G. Rigano L. Foti C. Grandolfo M. Veña G. A. Bonamonte D. Soleo L. Scorpiniti A. A. July 1996 Occupational sensitization to epoxy resin and reactive diluents in marble workers Contact Dermatitis 35 1 11–16 10.1111/j.1600-0536.1996.tb02259.x 0105-1873 8896948 7144917 Geier Johannes Lessmann Holger Hillen Uwe Skudlik Christoph Jappe Uta February 2016 Sensitization to reactive diluents and hardeners in epoxy resin systems. IVDK data 2002-2011. Part I: reaction frequencies Contact Dermatitis 74 2 83–93 10.1111/cod.12491 1600-0536 26538018 22297749 See also Epoxide Glycidol References External websites Hexion difunctional epoxy diluents https://web.archive.org/web/20220127104433/https://www.hexion.com/en-us/chemistry/epoxy-resins-curing-agents-modifiers/functional-modifiers/di-functional 2022-01-27 Epoxy diluent: 1,6-hexanediol diglycidyl ether Wanjie International Denacol epoxy diluent range Cargill Reactive diluents Category:Glycidyl ethers Category:Reactive diluents