2,6-Diisopropylaniline

Diisopropylaniline.png 2,6-(iPr)2C6H3NH2sample.jpg 2,6-Di(propan-2-yl)aniline 2,6-Diisopropylaniline2,6-DIPA 24544-04-5 32484 246-305-4 3183764 190BG0089I 13859730 1S/C12H19N/c1-8(2)10-6-5-7-11(9(3)4)12(10)13/h5-9H,13H2,1-4H3 WKBALTUBRZPIPZ-UHFFFAOYSA-N CC(C)C1=C(C(=CC=C1)C(C)C)N 12 19 1 colorless liquid -45 257 412 273 501 2,6-Diisopropylaniline is an organic compound with the formula H2NC6H3(CHMe2)2 (Me = CH3). It is a colorless liquid although, like many anilines, samples can appear yellow or brown. 2,6-Diisopropylaniline is a bulky aromatic amine that is often used to make ligands in coordination chemistry. The Schrock carbenes often are transition metal imido complexes derived from this aniline.R. R. Schrock Recent Advances in High Oxidation State Mo and W Imido Alkylidene Chemistry Chemical Reviews 2009 109 8 3211–3226 10.1021/cr800502p 19284732 2726908 Condensation with diacetylpyridine and acetylacetone gives, respectively, diiminopyridine10.1039/b107490c V. C. Gibson M. J. Humphries K. P. Tellmann D. F. Wass A. J. P. White D. J. Williams Chem. Commun. 2252 2001 The nature of the active species in bis(imino)pyridyl cobalt ethylene polymerisation catalysts 21 2252–2253 12240136 and NacNac ligands.D. J. Mindiola P. L. Holland T. H. Warren Complexes of Bulky β-Diketiminate Ligands. In Inorg. Synth. Inorganic Syntheses 2010 35 1–55 10.1002/9780470651568.ch1 9780471682554 left true true thumb|left|220px|Typical Schrock-style olefin metathesis catalysts feature bulky imides as spectator ligands. thumb|220px|Structure of the diamido-diimido complex W(NAr)2(N(H)Ar)2 (ArNH2 = 2,6-Diisopropylaniline.Tianniu Chen K.R. Sorasaenee Zhongzhi Wu J. B. Diminnie Ziling Xue Synthesis, Characterization and X-ray Structures of New Molybdenum Bis(imide) Amide and Silyl Complexes Inorg. Chim. Acta 2003 345 113 10.1016/S0020-1693(02)01271-9 References Category:Anilines Category:Isopropyl compounds