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1,3-Dithiole
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1,3-Dithiole.svg 100px Structure of 1,3-dithiole 2H-1,3-Dithiole 1,3-Dithiacyclopentene 288-74-4 correct FDA H3S82P9ZAT 5316944 4475898 1S/C3H4S2/c1-2-5-3-4-1/h1-2H,3H2 IVJFXSLMUSQZMC-UHFFFAOYSA-N C1SC=CS1
3 2 4
In organosulfur chemistry, 1,3-dithioles are a class of heterocycles based on the parent compound 1,3-dithiacyclopentene (also known as 1,3-dithiole). The ligand dmit2- is a 1,3-dithiole.Niels Svenstrup Jan Becher The Organic Chemistry of 1,3-Dithiole-2-thione-4,5-dithiolate (DMIT) Synthesis 1995 1995 3 215–235 10.1055/s-1995-3910 196762382 Heating solutions of Na2dmit gives the isomeric disulfide, a 1,2-dithiole.
thumb|left|Structure of the anion [Zn(dmit)2]2-, featuring two 1,3-dithiole-4,5-dithiolate ligands complexed to zinc.W.T.A. Harrison R.A. Howie J.L. Wardell S.M.S.V. Wardell N.M. Comerlato L.A.S. Costa A.C. Silvino A.I. de Oliveira R.M. Silva Polyhedron 19 821–827 10.1016/S0277-5387(00)00322-3 Crystal structures of three [bis(1,3-dithiole-2-thione-4,5-dithiolato)zincate]2− salts: [Q]2[Zn(dmit)2] (Q = 1,4-Me2-pyridinium or NEt4) and [PPh4]2[Zn(dmit)2]·DMSO. Comparison of the dianion packing arrangements in [Q]2[Zn(dmit)2]
References
Category:Dithioles