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2-Iodophenol
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2-Iodophenol.svg 120px 2-Iodophenol o-Iodophenol
ortho-Iodophenol
533-58-4 correct CAS 16706 225564 10784 10328 208-569-9 406034 C01874 F27L34A8B9 C1=CC=C(C(=C1)O)I 1S/C6H5IO/c7-5-3-1-2-4-6(5)8/h1-4,8H KQDJTBPASNJQFQ-UHFFFAOYSA-N
6 5 1 1 1.8757 g/cm3 (80 °C)Haynes, p. 3.324 43 186 (160 mmHg) 8.51Haynes, p. 5.93
exclamation mark 302 312 315 319 332 335 261 280 305+351+338
3-Iodophenol
4-Iodophenol
2-Fluorophenol
2-Chlorophenol
2-Bromophenol
2-Iodophenol (o-iodophenol) is an aromatic organic compound with the formula IC6H4OH. It is a pale yellow solid that melts near room temperature. It undergoes a variety of coupling reactions in which the iodine substituent is replaced by a new carbon group ortho to the hydroxy group of the phenol, which can be followed by cyclization to form heterocycles. https://www.sigmaaldrich.com/catalog/product/ALDRICH/281409 Sigma-Aldrich 2-Iodophenol
It can be prepared by treatment of 2-chloromercuriphenol with iodine:
ClHgC6H4OH + I2 -> IC6H4OH + HgCl(I)
Direct reaction of phenol with iodine gives a mixture of 2- and 4-iodo derivatives.Whitmore, F. C. Hanson, E. R. 10.15227/orgsyn.004.0037 free o-Iodophenol Organic Syntheses 1925 4 37
References
Cited sources
Haynes Haynes, William M. 2016 CRC Handbook of Chemistry and Physics 97th CRC Press 9781498754293
Category:2-Iodophenyl compounds
Category:2-Hydroxyphenyl compounds