1,4-Butanedithiol

1,4-butanedithiol.svg Butane-1,4-dithiolInternational Union of Pure and Applied Chemistry 2014 Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013 https://iupac.qmul.ac.uk/BlueBook/ The Royal Society of Chemistry P-63.1.5 10.1039/9781849733069 978-0-85404-182-4 1191-08-8 correct CAS 71479 214-728-3 79148 7JD227IUMC 1S/C4H10S2/c5-3-1-2-4-6/h5-6H,1-4H2 SMTOKHQOVJRXLK-UHFFFAOYSA-N C(CCS)CS 4 10 2 colorless liquid -53.9 195.5 1,4-Butanedithiol https://pubchem.ncbi.nlm.nih.gov/compound/79148#section=Safety-and-Hazards pubchem.ncbi.nlm.nih.gov en 07 Warning H315 H319 H335 P261 P264 P264+P265 P271 P280 P302+P352 P304+P340 P305+P351+P338 P319 P321 P332+P317 P337+P317 P362+P364 P403+P233 P405 P501 1,4-Butanedithiol is an organosulfur compound with the formula HSCH2CH2CH2CH2SH. It is a malodorous, colorless liquid that is highly soluble in organic solvents. The compound has found applications in biodegradable polymers.Türünç Oĝuz Meier Michael A. R. 2011 Thiol-ene vs. ADMET: a complementary approach to fatty acid-based biodegradable polymers http://xlink.rsc.org/?DOI=c0gc00773k Green Chemistry en 13 2 314 10.1039/c0gc00773k 1463-9262 subscription Reactions Alkylation with geminal dihalides gives 1,3-dithiepanes. Oxidation gives the cyclic disulfide 1,2-dithiane:10.1021/jo200496r Aerobic Oxidation of Thiols to Disulfides Catalyzed by Diaryl Tellurides under Photosensitized Conditions 2011 Oba Makoto Tanaka Kazuhito Nishiyama Kozaburo Ando Wataru The Journal of Organic Chemistry 76 10 4173–4177 21480642 HSCH2CH2CH2CH2SH + O -> S2(CH2)4 + H2O It forms self-assembled monolayers on gold.10.1021/ja4097384 Structural Study of Citrate Layers on Gold Nanoparticles: Role of Intermolecular Interactions in Stabilizing Nanoparticles 2014 Park Jong-Won Shumaker-Parry Jennifer S. Journal of the American Chemical Society 136 5 1907–1921 24422457 2014JAChS.136.1907P It is also used in polyadditions along with 1,4-butanediol to form sulfur-containing polyester and polyurethanes containing diisocyanate.Kojio Ken Nozaki Shuhei Takahara Atsushi Yamasaki Satoshi 2020 Influence of chemical structure of hard segments on physical properties of polyurethane elastomers: a review https://link.springer.com/10.1007/s10965-020-02090-9 Journal of Polymer Research en 27 6 10.1007/s10965-020-02090-9 218528107 1022-9760 subscription Sakhno T. V. Sakhno Yu. E. Kuchmiy S. Ya. 2023 Clusteroluminescence of Unconjugated Polymers: A Review https://link.springer.com/10.1007/s11237-023-09768-3 Theoretical and Experimental Chemistry en 59 2 75–106 10.1007/s11237-023-09768-3 260597152 0040-5760 subscription Manzano Verónica E. Synthesis and Applications of Carbohydrate-Based Polyurethanes 2017 http://link.springer.com/10.1007/978-3-319-61288-1_1 Industrial Applications of Renewable Biomass Products 1–43 Goyanes Silvia Nair 2023-12-05 Cham Springer International Publishing en 10.1007/978-3-319-61288-1_1 978-3-319-61287-4 Kolender Adriana A. Varela Oscar D’Accorso Norma Beatriz subscription Several of these polymers are considered biodegradable and many of their components are sourced from non-petroleum oils.Kreye Oliver Tóth Tommy Meier Michael A. R. 2011-09-01 Copolymers derived from rapeseed derivatives via ADMET and thiol-ene addition https://www.sciencedirect.com/science/article/pii/S0014305711002424 European Polymer Journal 47 9 1804–1816 10.1016/j.eurpolymj.2011.06.012 2011EurPJ..47.1804K 0014-3057 subscription Related compounds Dithiothreitol 1,3-Propanedithiol References Category:Reagents for organic chemistry Category:Alkanethiols Category:Foul-smelling chemicals