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2-Methyldodecane
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2-Methyldodecane-2D-skeletal.svg 2-Methyldodecane Isotridecane 1560-97-0 correct PubChem 15270 14535 271-369-5 A6360WD7Y3 1S/C13H28/c1-4-5-6-7-8-9-10-11-12-13(2)3/h13H,4-12H2,1-3H3 HGEMCUOAMCILCP-UHFFFAOYSA-N CCCCCCCCCCC(C)C
13 28 0.754 g·cm−3(20 °C)Bashkirov, A. N.; Shaikhutdinov, E. M.; Gilyarovskaya, L. A. Oxidation of monomethyl-substituted paraffin hydrocarbons in the liquid phase in the presence of boric acid. Doklady Akademii Nauk SSSR, 1963. 148. 1309-1311. 0002-3264. 103 - 104 C K(10.5 Torr)227.7±3.0 °C(760 Torr)Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2020 ACD/Labs). Retrieved from SciFinder. [2020-06-11]. 08 Danger 304 372 373 260 264 270 301+310 314 331 405 501
2-Methyldodecane, an organic compound with a chemical formula C13H28, is an isomer of tridecane. It is produced by the reaction of 1-bromodecane and diisopropyl zinc.Terao Jun Todo Hirohisa Watanabe Hideyuki Ikumi Aki Kambe Nobuaki 2004-11-19 Nickel-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Organozinc and Grignard Reagents with 1,3,8,10-Tetraenes as Additives https://onlinelibrary.wiley.com/doi/10.1002/anie.200460246 Angewandte Chemie International Edition en 43 45 6180–6182 10.1002/anie.200460246 1433-7851 15549748 subscription Reaction of decylmagnesium bromide and 2-bromopropane produce 2-methyldodecane too.Cahiez Gérard Chaboche Christophe Duplais Christophe Giulliani Arianna Moyeux Alban 2008-07-07 Cobalt-Catalyzed Cross-Coupling Reaction between Functionalized Primary and Secondary Alkyl Halides and Aliphatic Grignard Reagents https://onlinelibrary.wiley.com/doi/10.1002/adsc.200800166 Advanced Synthesis & Catalysis en 350 10 1484–1488 10.1002/adsc.200800166 subscription Another method to produce 2-methyldodecane is react 1-dodecene and trimethylaluminium.Mark Stefan Gaidzik Nikola Doye Sven Enders Markus 2009 Organochromium complexes as catalysts for the carboalumination of unactivated terminal olefins http://xlink.rsc.org/?DOI=b902609f Dalton Transactions en 25 4875–4877 10.1039/b902609f 1477-9226 19662278 2020-06-19 subscription
References
Category:Alkanes