(Norbornadiene)molybdenum tetracarbonyl

Mo(nbd)(CO)4.png Mo(nbd)(CO)4 sample (with spatula).jpg 12146-37-1 452413 11370028 DTXSID90153276 1S/C7H8.4CO.Mo/c1-2-7-4-3-6(1)5-7;4*1-2;/h1-4,6-7H,5H2;;;;; UZHYHBPCAGKHGZ-UHFFFAOYSA-N [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1C2C=CC1C=C2.[Mo] 11 8 1 4 07 Warning 302 312 315 319 332 335 261 264 270 271 280 301+312 302+352 304+312 304+340 305+351+338 312 321 322 330 332+313 337+313 362 363 403+233 405 501 (Norbornadiene)molybdenum tetracarbonyl is the organomolybdenum compound with the formula (C7H9)Mo(CO)4. Structurally, the compound consists of the norbornadiene bonded to a Mo(CO)4 fragment. The compound is a yellow, volatile solid. It is prepared by thermal or photochemical substitution of molybdenum hexacarbonyl.Ein neuer Weg zur Darstellung substituierter Metallcarbonyl-Komplexe von Chrom und Molybdän Chemische Berichte Helmut Werner Richard Prinz 1967 100 265–270 10.1002/cber.19671000131 The compound was originally examined as a potential antiknock agent.Cyclic diene metal carbonyl complexes Ihrman, Kryn G.; Coffield, Thomas H. Ethyl Corp. 1963-06-11 US 3093671 (Norbornadiene)molybdenum tetracarbonyl is a precursor to other derivatives of the type L2Mo(CO)4. This conversion exploits the lability of the diene ligand:Evidence for an Equilibrium between an N-Heterocyclic Carbene and Its Dimer in Solution Hahn F. Ekkehardt Wittenbecher Lars Le Van Duc Fröhlich Roland Angewandte Chemie International Edition 2000 39 3 541–544 10.1002/(SICI)1521-3773(20000204)39:3<541::AID-ANIE541>3.0.CO;2-B 10671250 (C7H9)Mo(CO)4 + 2 L → C7H9 + L2Mo(CO)4 References External links (Norbornadiene)molybdenum tetracarbonyl Category:Molybdenum(0) compounds Category:Carbonyl complexes Category:Octahedral compounds Category:Diene complexes Category:Organomolybdenum compounds