2-Picolylamine

2-aminomethylpyridine.svg 144px 1-(Pyridin-2-yl)methanamine 2-aminomethylpyridine 3731-51-9 correct FDA XK7252M2PA 18383 223-090-5 19509 81387 32189 C17926 1S/C6H8N2/c7-5-6-3-1-2-4-8-6/h1-4H,5,7H2 WOXFMYVTSLAQMO-UHFFFAOYSA-N C1=CC=NC(=C1)CN 6 8 2 1.049https://www.sigmaaldrich.com/US/en/product/aldrich/a65204 g/cm3 -20 203 05 07 Danger 314 319 335 260 261 264 271 280 301+330+331 303+361+353 304+340 305+351+338 310 312 321 337+313 363 403+233 405 501 2-Picolylamine is an organic compound with the formula H2NCH2C5H4N. A colorless liquid, it is a common bidentate ligand and a precursor to more complex multidentate ligands such as tris(2-pyridylmethyl)amine. It is usually prepared by hydrogenation of 2-cyanopyridine. One such complex is Baratta's catalyst RuCl2(PPh3)2(ampy) (ampy = 2-picolylamine) for transfer hydrogenation.10.1016/j.ccr.2015.04.007 Ruthenium and Osmium Complexes Containing 2-(aminomethyl)pyridine (Ampy)-Based Ligands in Catalysis Coordination Chemistry Reviews 300 29–85 2015 Chelucci Giorgio Baldino Salvatore Baratta Walter 2318/1693450 free Salts of the complex [Fe(pyCH2NH2)3]2+ exhibit spin crossover behavior, whereby the complex switches from high to low spin configurations, depending on the temperature.10.1016/S0010-8545(01)00381-2 Photoswitchable Coordination Compounds Coordination Chemistry Reviews 219 839–879 2001 Gütlich P. Safety The oral in quail is low, being 750 mg/kg.Shinkichi Shimizu Nanao Watanabe Toshiaki Kataoka Takayuki Shoji Nobuyuki Abe Sinji Morishita Hisao Ichimura Pyridine and Pyridine Derivatives 2007 10.1002/14356007.a22_399 References Category:2-Pyridyl compounds Category:Amines