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1,3-Diphenyltriazene
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1,3-Diphenyl-1-triazene.svg 1,3-Diphenyltriaz-1-ene Diazoaminobenzene 136-35-6 8689 205-240-1 5T4EEW75HJ 573540 8365 1S/C12H11N3/c1-3-7-11(8-4-1)13-15-14-12-9-5-2-6-10-12/h1-10H,(H,13,14) ALIFPGGMJDWMJH-UHFFFAOYSA-N C1=CC=C(C=C1)NN=NC2=CC=CC=C2
12 11 3 Pale yellow solid 1.29 g/cm3 95-96The Journal of Organic Chemistry 55 8 en 0022-3263 April 1990 2543–2545 10.1021/jo00295a056 https://pubs.acs.org/doi/abs/10.1021/jo00295a056 Application of the isoamyl nitrite-diiodomethane route to aryl iodides 2021-05-27 William B. Smith, Oliver Chenpu Ho subscription 180 decomposesShimura, Eiji. Preparation of electrophotographic toners using a foaming agent and an insulating substance. 1988. JP 63050863 A. 07 Warning 302 312 315 319 332 335 261 264 270 271 280 301+312 302+352 304+312 304+340 305+351+338 312 321 322 330 332+313 337+313 362 363 403+233 405 501
1,3-Diphenyltriazene is the organic compound with the formula PhN=N-N(H)Ph (Ph = C6H5). It is a prototypical triazene, i.e. a compound with the functional group RN=N-NR2. It is a pale yellow solid, prepared by the reaction of phenyldiazonium chloride with aniline. Hartman W. W. Dickey J. B. Diazoaminobenzene Organic Syntheses 14 24 1934 10.15227/orgsyn.014.0024 free It can be prepared from aniline in a one-pot reaction via partial diazotization.Kazem-Rostami M. Khazaei A. Moosavi-Zare A. R. Bayat M. Saednia S. 2012 Novel One-Pot Synthesis of Thiophenols from Related Triazenes under Mild Conditions Synlett 23 13 1893–1896 10.1055/s-0032-1316557 196805424 Hartman, W. W.; Dickey, J. B. 1934 Diazoaminobenzene Organic Syntheses 14 24 10.15227/orgsyn.014.0024 free
It is a planar molecule. The N-N distances are 1.287 and 1.337 Å.10.1002/zaac.201100227 Reaktionen von 1,3-Diphenyltriazenid mit Cu+ und Tl+ Zeitschrift für anorganische und allgemeine Chemie 637 1784–1789 2011 Lego Christian Neumüller Bernhard 12
References
Category:Phenyl compounds
Category:Azo compounds
Category:Triazenes