2,2'-Biphenylene phosphorochloridite

2,2′-Biphenylene phosphorochloridite Biphenolphosphochloridite.svg 6-Chloro-6H-dibenzo[d,f][1,3,2]dioxaphosphepine 1,1′-Biphenyl-2,2′-diyl phosphorochloridite 16611-68-0 612102 532081 929-115-2 DTXSID20884920 1S/C12H8ClO2P/c13-16-14-11-7-3-1-5-9(11)10-6-2-4-8-12(10)15-16/h1-8H RKNWJMHQLOIGIH-UHFFFAOYSA-N C1=CC=C2C(=C1)C3=CC=CC=C3OP(O2)Cl 12 8 0 1 1 white solid 63 2,2′-Biphenylene phosphorochloridite is the name for a polycyclic organophosphorus compound with the formula C12H8O2PCl. It is a precursor to diphosphite ligands such as BiPhePhos by reaction with suitable diols. 2,2′-Biphenylene phosphorochloridites, which is a white solid, is prepared from 2,2′-biphenol and phosphorus trichloride. It is prepared by the reaction of 2,2′-biphenol and phosphorus trichloride.10.1021/ja00058a079 Practical, High-Yield, Regioselective, Rhodium-Catalyzed Hydroformylation of Functionalized α-Olefins Journal of the American Chemical Society 115 2066–2068 1993 Cuny Gregory D. Buchwald Stephen L. 510.1021/OM950549K Bulky Diphosphite-Modified Rhodium Catalysts: Hydroformylation and Characterization Organometallics 15 835–847 1996 Van Rooy Annemiek Kamer Paul C. J. Van Leeuwen Piet W. N. M. Goubitz Kees Fraanje Jan Veldman Nora Spek Anthony L. 2 http://dare.uva.nl/personal/pure/en/publications/bulky-diphosphite-modified-rhodium-catalyst-hydroformylation-and-characterization(c06c2654-cecb-4e97-84ba-f1fdfb51ad35).html References Category:Phosphorus halides Category:Phosphorus(III) compounds