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411 REFERENCE · Wikipedia

2,4,6-Tri-tert-butylpyrimidine

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2,4,6-Tri-tert-butylpyrimidine Chemical structure of TTBP.svg 2,4,6-Tri-tert-butylpyrimidine 67490-21-5 correct CAS 2682941 628-674-7 3440137 1S/C16H28N2/c1-14(2,3)11-10-12(15(4,5)6)18-13(17-11)16(7,8)9/h10H,1-9H3 VYWSYEDVFVGRGG-UHFFFAOYSA-N CC(C)(C)C1=CC(=NC(=N1)C(C)(C)C)C(C)(C)C 16 28 2 White or colorless solid 77-78 2,4,6-Tri-tert-butylpyrimidine is the organic compound with the formula HC(ButC)2N2CtBu where tBu = (CH3)3C. It is a substituted derivative of the heterocycle pyrimidine. Known also as TTBP, this compound is of interest as a base that is sufficiently bulky to not bind boron trifluoride but still able to bind protons. It is less expensive that the related bulky derivatives of pyridine such as 2,6-di-tert-butylpyridine, 2,4,6-tri-tert-butylpyridine, and 2,6-di-tert-butyl-4-methylpyridine.10.1055/s-2001-10798 2,4,6-Tri-tert-butylpyrimidine (TTBP): A Cost Effective, Readily Available Alternative to the Hindered Base 2,6-Di-tert-butylpyridine and its 4-Substituted Derivatives in Glycosylation and Other Reactions 2001 Crich David Smith Mark Yao Qingjia Picione John Synthesis 2001 2 0323–0326 196775791 References Category:Pyrimidines Category:Reagents for organic chemistry Category:Non-nucleophilic bases Category:Tert-butyl compounds