1-Dodecene

1-Dodecene 1-dodecene.svg Molecular Model of Dodecene 2.jpg Dodec-1-ene 1-Dodeceneα-DodeceneDodecene-1Adacene 12Dodecylene 112-41-4 correct CAS correct FDA WYE669F3GR 89713 7891 203-968-4 1S/C12H24/c1-3-5-7-9-11-12-10-8-6-4-2/h3H,1,4-12H2,2H3 8183 CCCCCCCCCCC=C colorless liquid with a mild, pleasant odor.http://cameochemicals.noaa.gov/chemical/8597#section4 1-DODECENE | CAMEO Chemicals | NOAA 213.8˚Chttps://pubchem.ncbi.nlm.nih.gov/compound/8183 1-Dodecene 0.7584 g/cm3 12 24 -35.2 Insoluble Soluble in ethanol, ethyl ether, and acetone 0.0159 mm Hg at 25 °C 77 Irritates skin and eyes, harmful if swallowed, wear safety glasses and have adequate ventilation http://www.chemspider.com/Chemical-Structure.7891.html?rid=7fdae3b1-4195-4136-a364-be7c1b4abd95 Dodecene | C12H24 | ChemSpider 0 2 0 Alkenes OcteneNoneneUndeceneDodecene 1-Dodecene is an alkene with the formula C10H21CH=CH2, consisting of a chain of twelve carbon atoms ending with a double bond. While there are many isomers of dodecene depending on which carbon the double bond is placed, this isomer is of greater commercial importance. It is classified as an alpha-olefin. Alpha-olefins are distinguished by having a double bond at the primary or alpha (α) position. This location of a double bond enhances the reactivity of the compound and makes it useful for a number of applications, especially for the production of detergents.Kurt Kosswig,"Surfactants" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, 2005, Weinheim. 10.1002/14356007.a25_747 Production and reactions 1-Dodecene is commercially produced by oligomerization of ethylene via a number of processes. In the Shell Higher Olefin Process (SHOP), a nickel catalyst is employed. In processes developed by Gulf and by Ethyl Corporations, triethylaluminium is the catalyst. Similar to the SHOP method, these processes rely on ethylene insertion into an Al-alkyl bond competitively with beta-hydride elimination to give the alpha-olefin, regenerating an aluminium hydride. Other processes have been developed.10.1002/14356007.a13_227.pub3 Hydrocarbons Ullmann's Encyclopedia of Industrial Chemistry 2014 Schmidt Roland Griesbaum Karl Behr Arno Biedenkapp Dieter Voges Heinz-Werner Garbe Dorothea Paetz Christian Collin Gerd Mayer Dieter Höke Hartmut 1–74 9783527306732 http://www.chemsystems.com/about/cs/news/items/PERP%200607_5_AlphaOlefins.cfm ChemSystems: Return on Analysis for Investment in the Petrochemical Industry: Markets, Technology, Profitability and Prices 2012-10-19 https://web.archive.org/web/20110831182356/http://www.chemsystems.com/about/cs/news/items/PERP%200607_5_AlphaOlefins.cfm 2011-08-31 dead Tridecanal is produced by hydroformylation of 1-dodecene. References Category:Alkenes