(Cyclopentadienyl)titanium trichloride

Titanocene-trichloride-3D-balls.png Titanocene trichloride 1270-98-0 correct CAS correct FDA BPJ2QGJ6ZF 11127785 11601864 1S/C5H5.3ClH.Ti/c1-2-4-5-3-1;;;;/h1-5H;3*1H;/q;;;;+3/p-3 AENCLWKVWIIOQH-UHFFFAOYSA-K c1[cH-]ccc1.Cl[Ti+](Cl)Cl 5 5 1 3 orange solid 1.768 g/cm3 210 (Cyclopentadienyl)titanium trichloride is an organotitanium compound with the formula (C5H5)TiCl3. It is a moisture sensitive orange solid. The compound adopts a piano stool geometry.Rossini, A. J. Mills, R. W. Briscoe, G. A. Norton, E. L. Geier, S. J. Hung, I. Zheng, S. Autschbach, J. Schurko, R. W. 4 Solid-State Chlorine NMR of Group IV Transition Metal Organometallic Complexes Journal of the American Chemical Society 2009 131 9 3317–3330 10.1021/ja808390a 19256569 Preparation and reactions (C5H5)TiCl3 is prepared by the reaction of titanocene dichloride and titanium tetrachloride: (C5H5)2TiCl2 + TiCl4 → 2 (C5H5)TiCl3 The complex is electrophilic, readily forming alkoxide complexes upon treatment with alcohols.Trichloro(cyclopentadienyl)titanium EEROS Andreas Hafner Rudolf O. Duthaler 2001 10.1002/047084289X.rt202m 0-471-93623-5 Reduction of (cyclopentadienyl)titanium trichloride with zinc powder gives the polymeric Ti(III) derivative (cyclopentadienyl)titanium dichloride:10.1002/9780470132470.ch62 Inorganic Syntheses 2007 Lucas C. R. Green M. L. H. Some η-Cyclopentadienyl Complexes of Titanium(III) 237–240 1976 16 978-0-470-13178-7 (C5H5)TiCl3 + 0.5 Zn → 1/n [(C5H5)TiCl2]_{n} + ZnCl2 A related reduction can be effected with cobaltocene:10.1016/S0277-5387(00)80641-5 Synthesis of [Co(η5-C5H5)2][M(η5-C5H5)Cl3] salts (M = Ti or V): Crystal structure of [Co(η5-C5H5)2][Ti(η5-C5H5)Cl3] 1989 Hughes D.L. Jimenez-Tenorio M. Leigh G.J. Polyhedron 8 13–14 1780–1781 (C5H5)TiCl3 + (C5H5)2Co → [(C5H5)2Co]+[(C5H5)TiCl3]- Other evidence for the Lewis acidity of the trichloride is the ready formation of adducts with phosphine ligands:10.1021/ic00078a008 Radical Routes to Titanium(IV) Thiolate Complexes: Structure and Reactivity of ((η5--C5H5)TiIII and -TiIV Donor and Thiolate Derivatives 1993 Nadasdi T. Timothy Stephan Douglas W. Inorganic Chemistry 32 26 5933–5938 (C5H5)TiCl3 + P(CH3)3 → (C5H5)TiCl3(P(CH3)3 See also (Cyclopentadienyl)zirconium trichloride (Pentamethylcyclopentadienyl)titanium trichloride (Indenyl)titanium trichloride10.1002/9780470132630.ch36 Monoindenyltrichloride Complexes of Titanium(IV), Zirconium(IV), and Hafnium(IV) 215–221 1998 32 Morris Robert J. Shaw Scott L. Jefferis Jesse M. Storhoff James J. Goedde Dean M. Inorganic Syntheses 978-0-471-24921-4 References Category:Titanocenes Category:Chloro complexes Category:Titanium(IV) compounds