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1-Bromohexane
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Chemical compound
changed 477207159 1-Bromhexan.svg Structural formula of 1-Bromohexane skin-invert 1-Bromohexane-3D-balls.png correct ?? 160 Ball and stick model of 1-Bromohexane bg-transparent 1-Bromohexane-3D-spacefill.png correct ?? 160 Space-filling model of 1-Bromohexane bg-transparent 1-Bromohexane1-bromohexane - Compound Summary https://pubchem.ncbi.nlm.nih.gov/compound/8101 PubChem Compound National Center for Biotechnology Information 17 June 2012 USA 26 March 2005 Identification Bromohexane Hexyl bromide} 1-Hexyl bromide n-Hexyl bromide 111-25-1 correct CAS HxBrn-HxBrnHxBrnHxBr correct FDA WVA0FAX7GA 8101 7810 correct chemspider 203-850-2 1993 1-bromohexane MO0925000 1731290 CCCCCCBr 1S/C6H13Br/c1-2-3-4-5-6-7/h2-6H2,1H3 correct chemspider MNDIARAMWBIKFW-UHFFFAOYSA-N correct chemspider 6 13 1 Colorless liquid 1.176 g/mL 188.45 427 to 431 1.448 (20 °C, D) Insoluble Alcohol, ether −196.1–−192.9 kJ mol−1 −4026.2–−4023.0 kJ mol−1 452.92 J K−1 mol−1 219.7 J K−1 mol−1 flame exclamation mark WARNING 226 315 319 335 261 305+351+338 57 1 2 0 1.226 g/kg (IP, mouse) alkanes 1-Bromobutane 1-Bromododecane 2-Bromobutane 2-Bromohexane
1-Bromohexane is organobromine compound with formula Br(CH2)5CH3. It is a colorless liquid.
Synthesis and reactions
Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-Markovnikov addition, giving the 1-bromo derivative. Dagani M. J. Barda H. J. Benya T. J. Sanders D. C. Bromine Compounds 10.1002/14356007.a04_405
1-Bromohexane undergoes reactions expected of simple alkyl bromides. It can form Grignard reagents.Garst, J., Ungvary, F., Batlaw, R., & Lawrence, K. (1991). Solvent attack in Grignard reagent formation from bromocyclopropane and 1-bromohexane in diethyl ether. Journal of American Chemical Society, 113, 5392-5397. It reacts with potassium fluoride to give the corresponding fluorocarbons. Vogel A. I. Leicester J. Macey W. A. T. n-Hexyl Fluoride 36 1956 40 10.15227/orgsyn.036.0040
See also
1-Fluorohexane
1-Chlorohexane
1-Iodohexane
Bromoalkanes
Bromocyclohexane
Bromocyclopropane
References
Category:Bromoalkanes