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1,2-Bis(dicyclohexylphosphino)ethane
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Dcpe.svg Bis(dicyclohexylphosphino)ethane-3D-balls-by-AHRLS-2012.png (Ethane-1,2-diyl)bis(dicyclohexylphosphane) dcpe 23743-26-2 correct FDA DG2ZG8EGQ2 534202 465407 C1CCC(CC1)P(CCP(C2CCCCC2)C3CCCCC3)C4CCCCC4 1/C26H48P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h23-26H,1-22H2 BOUYBUIVMHNXQB-UHFFFAOYAM 1S/C26H48P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h23-26H,1-22H2 BOUYBUIVMHNXQB-UHFFFAOYSA-N C26H48P2 422.61 white solid 96-97
Bis(dicyclohexylphosphino)ethane, abbreviated dcpe, is an organophosphorus compound with the formula (C6H11)2PCH2CH2P(C6H11)2. It is a white solid that is soluble in nonpolar organic solvents.10.1002/047084289X.rn02031 1,2-Bis(dicyclohexylphosphino)ethane Encyclopedia of Reagents for Organic Synthesis 2017 Rouchet Jean-Baptiste 1–5 978-0-470-84289-8 The compound is used as a bulky and highly basic diphosphine ligand in coordination chemistry.Sowa, J. R., Jr., Zanotti, V., Facchin, G., Angelici, R. J., "Calorimetric studies of the heats of protonation of the metal in Fe(CO)3(bidentate phosphine, arsine) complexes: effects of chelate ligands on metal basicity", J. Am. Chem. Soc. 1992, 114, 160. 10.1021/ja00027a023
References
Category:Chelating agents
Category:Diphosphines
Category:1,2-Ethanediyl compounds