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2-Bromonaphthalene
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2-bromonaphthalene.svg 580-13-2 192643 10894 209-452-5 11372 SYU33I753N 1S/C10H7Br/c11-10-6-5-8-3-1-2-4-9(8)7-10/h1-7H APSMUYYLXZULMS-UHFFFAOYSA-N C1=CC=C2C=C(C=CC2=C1)Br
10 7 1 white solid 45-50 281–283 0.00347 mmHg
PubChem 2-Bromonaphthalene https://pubchem.ncbi.nlm.nih.gov/compound/11372 2026-04-14 pubchem.ncbi.nlm.nih.gov en 07 Warning H302 H319 P264 P264+P265 P270 P280 P301+P317 P305+P351+P338 P330 P337+P317 P501
2-Bromonaphthalene is an organic compound with the formula C10H7Br. It is one of two isomeric monobromonaphthalenes, the other being 1-bromonaphthalene. Under normal conditions, the substance is a colorless solid.
Synthesis and reactions
It is prepared by treatment of 2-naphthol with triphenylphosphine dibromide: 10.15227/orgsyn.049.0006 free 2-Bromonaphthalene Organic Syntheses 1969 49 6 J. P. Schaefer Jerry Higgins P. K. Shenoy
C10H7(OH) + (C6H5)3PBr2 → C10H7Br + (C6H5)3PO + HBr
It can also be prepared by a Sandmeyer reaction from 2-aminonaphthalene.H. Meislich, H. Nechamkin, J. Sharefkin: Organische Chemie. (= Schaum's outline). McGraw Hill, Düsseldorf 1980, ISBN 978-0-070-63425-1, S. 341.
It forms a Grignard reagent. (4R,5R)-2,2-Dimethyl-α,α,α',α'-Tetra(naphth-2-yl)-1,3-Dioxolane-4,5-Dimethanol from Dimethyl Tartrate and 2-Naphthyl Magnesium Bromide Organic Syntheses 1999 76 12 10.15227/orgsyn.076.0012 free Albert K. Beck Peter Gysi Luigi La Vecchia Dieter Seebach
References
Category:Bromoarenes
Category:2-Naphthyl compounds