(Triphenylphosphine)iron tetracarbonyl

FeP(CO)4.svg 120 35679-07-3 518983 4807513 1S/C18H15P.4CO.Fe/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;4*1-2;/h1-15H;;;;; GHXDZMLBRWBQAM-UHFFFAOYSA-N [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Fe] 22 15 1 4 1 white solid 262-266 (Triphenylphosphine)iron tetracarbonyl is a coordination complex with the formula Fe(CO)4(PPh3) (Ph = C6H5). An off-white solid, this complex is derived from iron pentacarbonyl by replacement of one carbonyl ligand by triphenylphosphine (PPh3). Synthesis and use The title complex can be prepared by reaction of iron pentacarbonyl or triiron dodecacarbonyl with triphenylphosphine:10.1002/9780470132395.ch49 Iron Carbonyl Complexes of Triphenylphosphine, Triphenylarsine, and Triphenylstibine 1966 Clifford A. F. Mukherjee A. K. Inorganic Syntheses 185–191 VIII 9780470131671 Fe3(CO)12 + 3 P(C6H5)3 → 3 Fe(CO)4(P(C6H5)3) The substitution is catalyzed by cobalt chloride.10.1002/9780470132579.ch12 Inorganic Syntheses 1989 26 Albers Michel O. Singleton Eric Coville Neil J. Tetracarbonyliron(0) Complexes Containing Group V Donor Ligands 59–64 9780470132579 (Triphenylphosphine)iron tetracarbonyl is an intermediate in the synthesis of bis(triphenylphosphine)iron tricarbonyl. Both the mono- and bis(triphenylphosphine) complexes were originally employed in pioneering research on homogeneous catalysis by Walter Reppe.Walter Reppe Walter Joachim Schweckendiek 10.1002/jlac.19485600104 Cyclisierende Polymerisation von Acetylen. III Benzol, Benzolderivate und hydroaromatische Verbindungen Justus Liebigs Annalen der Chemie 1948 560 104–116 References Category:Triphenylphosphine complexes Category:Iron carbonyl complexes