(Pentamethylcyclopentadienyl)titanium trichloride

(Pentamethylcyclopentadienyl)titanium trichloride Cp*TiCl3.svg Cp*TiCl3 12129-06-5 624-062-9 correct FDA RM8V7EFM46 16212911 11601864 3261 1S/C10H15.3ClH.Ti/c1-6-7(2)9(4)10(5)8(6)3;;;;/h1-5H3;3*1H;/q;;;;+3/p-3 QCEOZLISXJGWSW-UHFFFAOYSA-K CC1=C([C](C(=C1C)C)C)C.Cl[Ti](Cl)Cl 10 15 1 3 Orange solid 225 Trichloro(pentamethylcyclopentadienyl)titanium(IV) 446289 https://www.sigmaaldrich.com/catalog/product/aldrich/446289 Sigma-Aldrich 05 Danger 314 280 305+351+338 310 (Pentamethylcyclopentadienyl)titanium trichloride is an organotitanium compound with the formula Cp*TiCl3 (Cp* = C5(CH3)5). It is an orange solid. The compound adopts a piano stool geometry. An early synthesis involve the combination of lithium pentamethylcyclopentadienide and titanium tetrachloride.10.1016/S0022-328X(00)91042-8 Organometallic chemistry of the transition metals XXI. Some π-pentamethylcyclopentadienyl derivatives of various transition metals Journal of Organometallic Chemistry 8 2 287–297 1967 King R.B. Bisnette M.B. The compound is an intermediate in the synthesis of decamethyltitanocene dichloride. In the presence of organoaluminium compounds and other additives, it catalyzes the polymerization of alkenes.10.1021/ma00190a003 Stereospecific polymerization of styrene giving the syndiotactic polymer 1988 Ishihara N. Kuramoto M. Uoi M. Macromolecules 21 12 3356–3360 1988MaMol..21.3356I 10.1021/om020954t An Approach to Catalyst Design: Cyclopentadienyl-Titanium Phosphinimide Complexes in Ethylene Polymerization 2003 Stephan Douglas W. Stewart Jeffrey C. Guérin Frédéric Courtenay Silke Kickham James Hollink Emily Beddie Chad Hoskin Aaron Graham Todd Wei Pingrong Spence Rupert E. v. H. Xu Wei Koch Linda Gao Xiaoliang Harrison Daryll G. Organometallics 22 9 1937–1947 See also (Cyclopentadienyl)titanium trichloride References Category:Chloro complexes Category:Titanium compounds Category:Half sandwich compounds