(Benzylideneacetone)iron tricarbonyl

changed 440442353 (benzylideneacetone)iron-tricarbonyl-2D-skeletal.png (bda)Fe(CO)3-from-xtal-Mercury-3D-bs1.png correct ?? 38333-35-6 9578311 11403415 1S/C10H10O.3CO.Fe/c1-9(11)7-8-10-5-3-2-4-6-10;3*1-2;/h2-8H,1H3;;;;/b8-7+;;;; BVYZFTVCCNDAIM-YZNHWISSSA-N [Fe].[O+]#[C-].[O+]#[C-].[O+]#[C-].O=C(\C=C\c1ccccc1)C C13H10FeO4 286.060 Red solid 88 to 89 slightly soluble (Benzylideneacetone)iron tricarbonyl is the organoiron compound with the formula (C6H5CH=CHC(O)CH3)Fe(CO)3. It is a reagent for transferring the Fe(CO)3 unit.Knölker Hans-Joachim https://onlinelibrary.wiley.com/doi/10.1002/047084289X.rb058 (η 4 -Benzylideneacetone)tricarbonyliron (η4-Benzylideneacetone)tricarbonyliron 2001-04-15 John Wiley & Sons, Ltd 978-0-471-93623-7 John Wiley & Sons, Ltd Chichester, UK en 10.1002/047084289x.rb058 This red-colored compound is commonly abbreviated (bda)Fe(CO)3. Structure and bonding (bda)Fe(CO)3 is an example of a complex of an η2-ketone. It is a piano stool complex. The compound is characterized by IR bands at 2065, 2005, and 1985 cm−1 (cyclohexane solution), the three bands being indicative of the low symmetry of the complex, which is chiral. Synthesis, reactions, related reagents left|thumb|Crystals of (Benzylideneacetone)iron tricarbonyl It is prepared by the reaction of Fe2(CO)9 with benzylideneacetone.Domingos A. J. P. Inorg. Synth. Howell J. A. S. Johnson B. F. G. Lewis J. 1990 9780470132593 Inorganic Syntheses 28 52–55 Reagents for the Synthesis of η-Diene Complexes of Tricarbonyliron and Tricarbonylruthenium 10.1002/9780470132593.ch11 (bda)Fe(CO)3 sometimes reacts with Lewis bases to give adducts without displacement of the bda.A.S. Howell James Kola John C. Dixon Denis T. Burkinshaw Philip M. Thomas Marion J. 1984 The kinetics and mechanism of diene exchange in (η4-enone) Fe(CO)2L complexes (L = phosphine, phosphite) https://linkinghub.elsevier.com/retrieve/pii/0022328X84801138 Journal of Organometallic Chemistry en 266 1 83–96 10.1016/0022-328X(84)80113-8 subscription The reagents of the type (bda)Fe(CO)2(PR3) function as sources of "Fe(CO)2(PR3)" (R = aryl, etc.).Johnson Brian F. G. Lewis Jack Stephenson G. Richard Vichi Eduardo J. S. 1978 Preparation and reactions of triphenylphosphine and triphenyl phosphite complexes of (benzylideneacetone)dicarbonyliron(0) http://xlink.rsc.org/?DOI=dt9780000369 Journal of the Chemical Society, Dalton Transactions en 5 369–373 10.1039/dt9780000369 0300-9246 subscription Other sources of Fe(CO)3 are Fe2(CO)9 and Fe(CO)3(cyclooctene)2. The latter is highly reactive and thermally sensitive. Imine derivatives of cinnamaldehyde, e.g. C6H5CH=CHC(H)=NC6H5, also form reactive Fe(CO)3 adducts, which have been shown to be superior in some ways to (bda)Fe(CO)3.Knölker Hans-Joachim Braier Arnold Bröcher Dirk J. Cämmerer Simon Fröhner Wolfgang Gonser Peter Hermann Holger Herzberg Daniela Reddy Kethiri R. Rohde Guy 2001-07-01 Recent applications of tricarbonyliron-diene complexes to organic synthesis Pure and Applied Chemistry 73 7 1075–1086 10.1351/pac200173071075 1365-3075 98692646 free References Further reading Alcock Nathaniel W. Richards Christopher J. Thomas Susan E. 1991 Preparation of tricarbonyl(.eta.4-vinylketene)iron(0) complexes from tricarbonyl(.eta.4-vinyl ketone)iron(0) complexes and their subsequent conversion to tricarbonyl(.eta.4-vinylketenimine)iron(0) complexes https://pubs.acs.org/doi/abs/10.1021/om00047a054 Organometallics en 10 1 231–238 10.1021/om00047a054 0276-7333 subscription Category:Organoiron compounds Category:Carbonyl complexes Category:Iron(0) compounds Category:Enones Category:Phenyl compounds