(Cycloheptatrienyl)(cyclopentadienyl)vanadium

(Cycloheptatrienyl)(cyclopentadienyl)vanadium Trovacene.svg 130 trovacene, TVC 12636-68-9 10138242 153696716 1S/C7H7.C5H5.V/c1-2-4-6-7-5-3-1;1-2-4-5-3-1;/h1-5H,6H2;1-5H;/q2*-1;+2 XTKKHYRECKNZQX-UHFFFAOYSA-N C1C=CC=CC=[C-]1.[CH-]1C=CC=C1.[V+2] 12 12 1 purple solid 1.447 g/cm3 (Cycloheptatrienyl)(cyclopentadienyl)vanadium is an organovanadium compound with the formula V(C5H5)(C7H7). It is a purple, paramagnetic, sublimable solid that is sensitive toward air. The structure has been confirmed by X-ray crystallography.10.1021/ja00887a030 The Molecular and Crystal Structures of π-Cyclopentadienyl π-Cycloheptatrienyl Vanadium 1963 Engebretson Gordon. Rundle R. E. Journal of the American Chemical Society 85 4 481–482 This sandwich complex features cyclopentadienyl and cycloheptatrienyl ligands bound to vanadium. It was first prepared by heating a mixture of cycloheptatriene and cyclopentadienylvanadium tetracarbonyl.10.1021/ja01528a063 π-Cylopentadienyl-π-Cycloheptatrienyl Vanadium 1959 King R. B. Stone F. G. A. Journal of the American Chemical Society 81 19 5263–5264 Many derivatives of trovacene are prepared by lithiation of the cyclopentadienyl ring.10.1002/ejic.201200310 α,ω-Di([5]trovacenyl) Sulfides TVC–Sn–TVC (n = 1–4) and TVC–SCH2S–TVC: A Study in Intramolecular Communication 2012 Elschenbroich Christoph Lu Feng Harms Klaus Burghaus Olaf Pietzonka Clemens Pebler Jürgen European Journal of Inorganic Chemistry 2012 24 3929–3936 See also (Cycloheptatrienyl)(cyclopentadienyl)titanium References Category:Organovanadium compounds Category:Cyclopentadienyl complexes Category:Cycloheptatrienyl complexes Category:Sandwich compounds