(Benzene)ruthenium dichloride dimer

changed 477199982 (benzene)ruthenium dichloride dimer (C6H6)RuCl2dimer.png YASDIG.png Dichloro(benzene)ruthenium(II) dimer, bis(η6-benzene)di-μ-chlorodichlorodiruthenium, (benzene)dichlororuthenium dimer, benzeneruthenium dichloride dimer, benzeneruthenium(II) chloride dimer 37366-09-9 correct CAS 9137359 626-792-3 10962144 1S/2C6H6.4ClH.2Ru/c2*1-2-4-6-5-3-1;;;;;;/h2*1-6H;4*1H;;/q;;;;;;2*+2/p-4 YGXMUPKIEHNBNQ-UHFFFAOYSA-J C1=CC=CC=C1.C1=CC=CC=C1.Cl[Ru]Cl.Cl[Ru]Cl 12 12 4 2 Red-brown solid 2.343 g/cm3 Slightly, with hydrolysis decomposes 07 Warning 315 319 335 261 264 271 280 302+352 304+340 305+351+338 312 321 332+313 337+313 362 403+233 405 501 (Benzene)ruthenium dichloride dimer is the organoruthenium compound with the formula [(C6H6)RuCl2]2. This red-coloured, diamagnetic solid is a reagent in organometallic chemistry and homogeneous catalysis. Preparation, structure, and reactions The dimer is prepared by the reaction of cyclohexadienes with hydrated ruthenium trichloride.Bennett M. A. Huang T. N. Matheson T. W. Smith A. K. (η6-Hexamethylbenzene)ruthenium Complexes 16. (η 6 -Hexamethylbenzene)Ruthenium Complexes Inorganic Syntheses 1982 21 74–78 10.1002/9780470132524.ch16 9780471865209 As verified by X-ray crystallography, each Ru center is coordinated to three chloride ligands and a η6-benzene.J. Canivet B. Therrien G. Suss-Fink 62686720 Di-μ-chlorobis[(η6-benzene) chlororuthenium(II)] Chloroform Disolvate Acta Crystallographica Section E 2005 61 6 m1090 10.1107/S1600536805014157 The complex can be viewed as an edge-shared bioctahedral structure. (Benzene)ruthenium dichloride dimer reacts with Lewis bases to give monometallic adducts: [(C6H6)RuCl2]2 + 2 PPh3 → 2 (C6H6)RuCl2(PPh3) Related compounds (Cymene)ruthenium dichloride dimer, a more soluble analogue of (benzene)ruthenium dichloride dimer. (Mesitylene)ruthenium dichloride dimer, another more soluble derivative.10.1002/047084289X.rn01290 Dichloro(mesitylene)ruthenium Dimer Encyclopedia of Reagents for Organic Synthesis 2011 Carole William A. Colacot Thomas J. 978-0471936237 References Category:Organoruthenium compounds Category:Chloro complexes Category:Dimers (chemistry) Category:Half sandwich compounds Category:Ruthenium(II) compounds