2-(Diphenylphosphino)anisole

Ph2PAn ligand.png (2-Methoxyphenyl)di(phenyl)phosphane 53111-20-9 603401 524530 625-558-8 1S/C19H17OP/c1-20-18-14-8-9-15-19(18)21(16-10-4-2-5-11-16)17-12-6-3-7-13-17/h2-15H,1H3 GBXNVYBGIFEOEM-UHFFFAOYSA-N COc1ccccc1P(c2ccccc2)c3ccccc3 19 17 1 1 white solid 1.188 g/cm310.1002/1099-0682(200012)2000:12<2607::AID-EJIC2607>3.0.CO;2-R Structural and Theoretical Studies ofortho-Substituted Triphenylphosphane Ligands and Their Rhodium(I) Complexes 2000 Suomalainen Pekka Jääskeläinen Sirpa Haukka Matti Laitinen Riitta H. Pursiainen Jouni Pakkanen Tapani A. European Journal of Inorganic Chemistry 2000 12 2607–2613 07 Warning 315 319 335 261 264 271 280 302+352 304+340 305+351+338 312 321 332+313 337+313 362 403+233 405 501 2-(Diphenylphosphino)anisole is the organophosphorus compound with the formula (C6H5)2PC6H4-2-OCH3. It is a white solid that is soluble in organic solvents. The compound is used as a ligand in organometallic chemistry and homogeneous catalysis. It is the prototypical hemilabile ligand. Jeffrey J. C. Rauchfuss T. B. 10.1021/ic50200a004 Metal Complexes of Hemilabile Ligands. Reactivity and Structure of Dichlorobis(o-(diphenylphosphino)anisole)ruthenium(II) Inorganic Chemistry 18 2658–2666 1979 10 This compound is prepared from 2-bromoanisole. Related ligands Tris(4-methoxyphenyl)phosphine Triphenylphosphine References Category:Tertiary phosphines Category:Phenyl compounds Category:2-Methoxyphenyl compounds