1,3-Diaminopropane

changed 477205113 1,3-Diaminopropane.svg correct ?? 160 Structural formula of 1,3-diaminopropane skin-invert Propane-1,3-diamine Propandiamine 1,3-Propylenediamine Trimethylenediamine 3-Aminopropylamine 109-76-2 correct CAS correct FDA CB3ISL56KG 428 415 correct chemspider 203-702-7 2922 C00986 correct kegg trimethylenediamine 15725 correct EBI 174324 correct EBI TX6825000 605277 1298 B00214 NCCCN 1S/C3H10N2/c4-2-1-3-5/h1-5H2 correct chemspider XFNJVJPLKCPIBV-UHFFFAOYSA-N correct chemspider 3 10 2 Colourless liquid Fishy, ammoniacal 0.888 g mL−1 261.15 413.2 −1.4 <1.1 kPa or 11.5 mm Hg(at 20 °C) 1.458 −58.1·10−6 cm3/mol flame corrosion skull and crossbones DANGER 226 302 310 314 280 302+350 305+351+338 310 3 3 0 51 350 2.8–15.2% 177 mg kg−1 (dermal, rabbit) 700 mg kg−1 (oral, rat) alkanamines Ethylamine Ethylenediamine Propylamine Isopropylamine 1,2-Diaminopropane Isobutylamine tert-Butylamine n-Butylamine sec-Butylamine Putrescine 2-Methyl-2-nitrosopropane 1,3-Diaminopropane, also known as trimethylenediamine, is a simple diamine with the formula H2N(CH2)3NH2. A colourless liquid with a fishy odor, it is soluble in water and many polar organic solvents. It is isomeric with 1,2-diaminopropane. Both are building blocks in the synthesis of heterocycles, such as those used in textile finishing, and coordination complexes. It is prepared by the amination of acrylonitrile followed by hydrogenation of the resulting aminopropionitrile.Karsten Eller, Erhard Henkes, Roland Rossbacher, Hartmut Höke "Amines, Aliphatic" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005. 10.1002/14356007.a02_001 The potassium salt was used in the alkyne zipper reaction. C. A. Brown and A. Yamashita Saline hydrides and superbases in organic reactions. IX. Acetylene zipper. Exceptionally facile contrathermodynamic multipositional isomeriazation of alkynes with potassium 3-aminopropylamide 1975 J. Am. Chem. Soc. 97 4 891–892 10.1021/ja00837a034 Applications Spermidines, imipramine, and phenothiazine-type structures, eprobemide, cannabisativine, codonocarpine, palustridine, palustrine, oncinotine & pithecolobine have 1,3-diaminopropane in their structures. Safety 1,3-Diaminopropane is toxic on skin exposure with an of 177 mg kg−1 (dermal, rabbit) References Category:Diamines Category:NMDA receptor antagonists Category:1,3-Propanediyl compounds Category:Foul-smelling chemicals