2,5-Furandicarboxaldehyde

2,5-Furandicarboxaldehyde.png Furan-2,5-dicarbaldehyde 2,5-Diformylfuran 823-82-5 correct CAS FDC 83385 63172 212-520-7 C20899 69980 L4HT8N2Z72 1S/C6H4O3/c7-3-5-1-2-6(4-8)9-5/h1-4H KUCOHFSKRZZVRO-UHFFFAOYSA-N C1=C(OC(=C1)C=O)C=O 6 4 3 07 Warning 315 319 335 261 264 271 280 302+352 305+351+338 2,5-Furandicarboxaldehyde (FDC) is an organic compound with the molecular formula C4H2O(CHO)2. It consists of a furan ring with aldehyde groups on the 2 and 5 position. It is therefore classified as a dialdehyde. Synthesis 2,5-Furandicarboxaldehyde is an oxidation product of 5-hydroxymethyl furfural (HMF), which in turn can be prepared from fructose. Alternatively, methods have been developed to convert fructose in one step to 2,5-furandicarboxaldehyde.10.1021/acssuschemeng.8b03470 One-Step Approach to 2,5-Diformylfuran from Fructose over Molybdenum Oxides Supported on Carbon Spheres 2019 Zhou Chunmei Zhao Jun Sun Haolin Song Yu Wan Xiaoyue Lin Hongfei Yang Yanhui ACS Sustainable Chemistry & Engineering 7 315–323 The conversion from fructose to HMF and FDC can be performed relatively efficiently and following the principles of green chemistry. As such, these materials are often considered as "greener" bio-based alternatives.November 2023 Applications 2,5-Furandicarboxaldehyde can be used in the preparation of polyimine vitrimers. 10.1039/C9GC00540D A fully bio-based polyimine vitrimer derived from fructose 2019 Dhers S. Vantomme G. Avérous L. Green Chemistry 12 7 35676–35684 104336119 https://pure.tue.nl/ws/files/129613047/c9gc00540d.pdf It can also be applied as an alternative to glutaraldehyde as crosslinking agent for covalent enzyme immobilisation. 10.1039/D2RA07153C 2,5-Furandicarboxaldehyde as a bio-based crosslinking agent replacing glutaraldehyde for covalent enzyme immobilization 2022 Danielli C. Van Langen L. Boes D. Asora F. Anselmi S. Provenza F. Renzi M. Gardossi L. RSC Adv. 21 7 1596–1601 36545099 9748790 2022RSCAd..1235676D See also Terephthalaldehyde (TA) 2,5-Furandicarboxylic acid (FDCA) References Category:Furans Category:Aromatic aldehydes