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1,2,3,4-Butanetetracarboxylic acid
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ButanetetracarboxylicAcid.svg Butane-1,2,3,4-tetracarboxylic acid 1703-58-8 unspecified stereochemistry 4534-68-3 meso 4799-96-6 (R,R)-enantiomer correct FDA 5A3KY454MZ 216-938-0 1574612 14804 15560 1S/C8H10O8/c9-5(10)1-3(7(13)14)4(8(15)16)2-6(11)12/h3-4H,1-2H2,(H,9,10)(H,11,12)(H,13,14)(H,15,16) GGAUUQHSCNMCAU-UHFFFAOYSA-N C(C(C(CC(=O)O)C(=O)O)C(=O)O)C(=O)O
8 10 8 White solid 236 246 ºC for meso227-230 ºC for (R,R)
1,2,3,4-Butanetetracarboxylic acid is an organic compound with the formula (CH(CO2H)CH2CO2H)2. It is one of the simplest stable tetracarboxylic acids. The compound exists as two diastereomers, meso and the (R,R)/(S,S) pair. All are white solids. The compound is produced by oxidation of tetrahydrophthalic anhydride.
Uses and reactions
Among the several possible uses, it has been repeatedly investigated in the textile industry,10.1016/j.carbpol.2005.02.019 The Antimicrobial Activity of Cotton Fabrics Treated with Different Crosslinking Agents and Chitosan 2005 Eltahlawy K. Elbendary M. Elhendawy A. Hudson S. Carbohydrate Polymers 60 4 421–430 e.g., for permanent press clothing.10.1177/004051758805800809 Tetracarboxylic Acids as Formaldehyde-Free Durable Press Finishing Agents 1988 Welch Clark M. Textile Research Journal 58 8 480–486 As expected for a polycarboxylate, it binds zinc to afford coordination polymers.10.1039/b716657e Syntheses, Structures and Luminescent Properties of Zinc(II) and Cadmium(II) Coordination Complexes Based on New Bis(imidazolyl)ether and Different Carboxylate Ligands 2008 Wei Guo-Hua Yang Jin Ma Jian-Fang Liu Ying-Ying Li Shun-Li Zhang Lai-Ping Dalton Transactions 23 3080–3092 18521450
It forms a dianhydride (RN 4534-73-0), which consists of two succinic anhydride-like rings.10.1107/s0567740871002577 The Crystal Structure of Butane-1,2,3,4-tetracarboxylic Dianhydride 1971 Nagao R. Marumo F. Saito Y. Asahara T. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 27 3 569–572 1971AcCrB..27..569N
References
Category:Tetracarboxylic acids
Category:Textiles