2-Bromoanisole

2-Bromoanisole.svg 133 px 1-Bromo-2-methoxybenzene 578-57-4 correct FDA X3XAZ6R3FL 209-425-8 11358 13881329 1S/C7H7BrO/c1-9-7-5-3-2-4-6(7)8/h2-5H,1H3 HTDQSWDEWGSAMN-UHFFFAOYSA-N COC1=CC=CC=C1Br 7 7 1 1 Colorless liquid 2.5 216 09 Warning 411 273 391 501 2-Bromoanisole is an organobromide with the formula BrC6H4OCH3. A colorless liquid, it is one of three isomers of bromoanisole, the others being 3-bromoanisole and 4-bromoanisole. It is a standard coupling partner in metal catalyzed coupling reactions. These reactions include Heck reactions, Buchwald-Hartwig coupling,10.1021/ja016226z A General and Efficient Copper Catalyst for the Amidation of Aryl Halides and theN-Arylation of Nitrogen Heterocycles 2001 Klapars Artis Antilla Jon C. Huang Xiaohua Buchwald Stephen L. Journal of the American Chemical Society 123 31 7727–7729 11481007 Suzuki couplings, and Ullmann condensations.10.15227/orgsyn.082.0069 free Preparation of 1-Methoxy-2-(4-Methoxyphenoxy)Benzene Organic Syntheses 2005 82 69 Elizabeth Buck Zhiguo J. Song The corresponding Grignard reagent readily forms. It is a precursor to o-anisaldehyde.10.15227/orgsyn.044.0004 free O-Anisaldehyde A. J. Sisti Organic Syntheses 1964 44 410.15227/orgsyn.054.0042 free Aldehydes from 4,4-Dimethyl-2-oxazoline and Grignard Reagents: O-Anisaldehyde Organic Syntheses 1974 54 42 R. S. Brinkmeyer E. W. Collington A. I. Meyers References Category:2-Methoxyphenyl compounds Category:2-Bromophenyl compounds