(Cyclooctatetraene)iron tricarbonyl

Fe(cot)(CO)3.png 148px Fe(COT)(CO)3.jpg 166 px Tricarbonyl(cyclooctatetraene)iron 12093-05-9 621-975-4 11436476 9611340 1S/C8H8.3CO.Fe/c1-2-4-6-8-7-5-3-1;3*1-2;/h1-8H;;;;/b2-1-,3-1?,4-2?,5-3-,6-4-,7-5?,8-6?,8-7-;;;; XAOCYVWRKJTXOL-JGZYGLCTSA-N [C]=O.[C]=O.[C]=O.C\1=C\C=C/C=C\C=C1.[Fe] 11 8 3 1 orange solid 07 Warning 302 312 332 261 264 270 271 280 301+312 302+352 304+312 304+340 312 322 330 363 501 Tris(cyclooctatetraene)triiron (Cyclooctatetraene)iron tricarbonyl is the organoiron compound with the formula (C8H8)Fe(CO)3. Like other examples of (diene)Fe(CO)3 complexes, it is an orange, diamagnetic solid. Although several isomers are possible, only the η4-C8H8 complex is observed. The complex is an example of a ring-whizzer, since, on the NMR time-scale, the Fe(CO)3 center migrates around the rim of the cyclooctatetraene ligand.10.1021/ja00422a022 Carbon-13 Nuclear Magnetic Resonance Study of the Fluxional Behavior of Cyclooctatetraenetricarbonyliron and -Ruthenium Journal of the American Chemical Society 98 6 1413–1417 1976 Cotton F. Albert Hunter Douglas L. 1976JAChS..98.1413C References Category:Carbonyl complexes Category:Organoiron compounds Category:Half sandwich compounds Category:Iron(0) compounds Category:Eight-membered rings